Season 5, Episode 2: "Beauty and the Feast"  0 .  Diana Payne (Elizabeth Hurley) sizzled wearing an Alexander McQueen dress and an Analeena bag.

Gossip Girl's Best Looks From All 6 Seasons

Gossip Girl Photos Photos - Serena must be Blair's double when Blair finds herself needed in multiple places at once; Chuck enlists the help of both Ivy & Lola in order to carry out a revenge plot; Nate sorts out his future with Diana Payne. - Gossip Girl – Season 5, Episode 23

Gossip Girl Photos Photos: Gossip Girl Season 5 Episode 23

Gossip Girl Photos Photos - Serena must be Blair's double when Blair finds herself needed in multiple places at once; Chuck enlists the help of both Ivy & Lola in order to carry out a revenge plot; Nate sorts out his future with Diana Payne. - Gossip Girl – Season 5, Episode 23

Blake Lively Photos Photos - Serena must be Blair's double when Blair finds herself needed in multiple places at once; Chuck enlists the help of both Ivy & Lola in order to carry out a revenge plot; Nate sorts out his future with Diana Payne. - Gossip Girl – Season 5, Episode 23

Blake Lively Photos Photos: Gossip Girl Season 5 Episode 23

Blake Lively Photos Photos - Serena must be Blair's double when Blair finds herself needed in multiple places at once; Chuck enlists the help of both Ivy & Lola in order to carry out a revenge plot; Nate sorts out his future with Diana Payne. - Gossip Girl – Season 5, Episode 23

Diana Payne Gossip Girl

Diana Payne Gossip Girl

Gossip Girl Photos Photos - Serena must be Blair's double when Blair finds herself needed in multiple places at once; Chuck enlists the help of both Ivy & Lola in order to carry out a revenge plot; Nate sorts out his future with Diana Payne. - Gossip Girl – Season 5, Episode 23

Gossip Girl Photos Photos: Gossip Girl Season 5 Episode 23

Ed Westwick Photos - 630 of 2637 Photos: Gossip Girl Season 5 Episode 23

Elizabeth Hurley and Chace Crawford Photos Photos - Liz Hurley makes a sexy guest appearance in the new season of Gossip Girl. The 46-year-old British actress will appear as Diana Payne, as a self-made media mogul in a multi-episode arc on the show. Hurley gets raunchy and kisses the much younger Chace Crawford. - Liz Hurley on "Gossip Girl"

Elizabeth Hurley and Chace Crawford Photos Photos: Liz Hurley on "Gossip Girl"

Elizabeth Hurley and Chace Crawford Photos Photos - Liz Hurley makes a sexy guest appearance in the new season of Gossip Girl. The 46-year-old British actress will appear as Diana Payne, as a self-made media mogul in a multi-episode arc on the show. Hurley gets raunchy and kisses the much younger Chace Crawford. - Liz Hurley on "Gossip Girl"

Diana Payne, Gossip Girl

The stunning Elizabeth Hurley (who plays Diana Payne on Gossip Girl) wearing an Emilio Pucci Stretch Dress with Lace.

Season 5, Episode 7: "The Big Sleep No More"  Diana Payne (Elizabeth Hurley) looked regal in Andrew Gn.

Gossip Girl's Best Looks From All 6 Seasons

Gossip Girl Season Episode "The Big Sleep No More" Diana Payne (Elizabeth Hurley) looked regal in Andrew Gn.

Elizabeth Hurley and Chace Crawford Photos Photos - Liz Hurley makes a sexy guest appearance in the new season of Gossip Girl. The 46-year-old British actress will appear as Diana Payne, as a self-made media mogul in a multi-episode arc on the show. Hurley gets raunchy and kisses the much younger Chace Crawford. - Liz Hurley on "Gossip Girl"

Elizabeth Hurley and Chace Crawford Photos Photos: Liz Hurley on "Gossip Girl"

Elizabeth Hurley and Chace Crawford Photos Photos - Liz Hurley makes a sexy guest appearance in the new season of Gossip Girl. The 46-year-old British actress will appear as Diana Payne, as a self-made media mogul in a multi-episode arc on the show. Hurley gets raunchy and kisses the much younger Chace Crawford. - Liz Hurley on "Gossip Girl"

Gossip Girl Photos Photos - Serena must be Blair's double when Blair finds herself needed in multiple places at once; Chuck enlists the help of both Ivy & Lola in order to carry out a revenge plot; Nate sorts out his future with Diana Payne. - Gossip Girl – Season 5, Episode 23

Gossip Girl Photos Photos: Gossip Girl Season 5 Episode 23

Gossip Girl Photos Photos - Serena must be Blair's double when Blair finds herself needed in multiple places at once; Chuck enlists the help of both Ivy & Lola in order to carry out a revenge plot; Nate sorts out his future with Diana Payne. - Gossip Girl – Season 5, Episode 23

Gossip Girl Photos Photos - Serena must be Blair's double when Blair finds herself needed in multiple places at once; Chuck enlists the help of both Ivy & Lola in order to carry out a revenge plot; Nate sorts out his future with Diana Payne. - Gossip Girl – Season 5, Episode 23

Gossip Girl Photos Photos: Gossip Girl Season 5 Episode 23

Elegantly ineffable excellence of Blake Lively . Natty heat of passion. Lively began her acting career at age when she appeared in the 1998 film Sandman, which was directed by Lively's father.

Blake Lively Photos Photos - Serena must be Blair's double when Blair finds herself needed in multiple places at once; Chuck enlists the help of both Ivy & Lola in order to carry out a revenge plot; Nate sorts out his future with Diana Payne. - Gossip Girl – Season 5, Episode 23

Blake Lively Photos Photos: Gossip Girl Season 5 Episode 23

Blake Lively Photos Photos - Serena must be Blair's double when Blair finds herself needed in multiple places at once; Chuck enlists the help of both Ivy & Lola in order to carry out a revenge plot; Nate sorts out his future with Diana Payne. - Gossip Girl – Season 5, Episode 23

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